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Car

g

o and

H

a

z

ardous Materials

BOS-

P

RD-2

6

.900

6

12

x

T

an

k

s

wh

i

ch

h

a

v

e

co

n

t

a

i

ned

Zi

n

c

B

rom

i

de

shall

b

e d

r

a

i

ned as

much

as

po

ss

i

b

l

e

pr

i

or

to w

as

h

i

n

g

;

x

I

f

a

v

esse

l’

s

c

a

rgo

pump

c

ann

ot

r

e

mov

e

a

ll

but

th

e

s

m

a

ll

es

t

a

mou

n

t

of

br

i

ne

,

th

en

co

ns

i

de

r

a

t

i

o

n

shall

b

e

g

i

v

en

to

th

e

u

se

of

port

a

b

l

e

pump

s

to

ens

ur

e

as

li

tt

l

e

r

es

i

d

u

e as

po

ss

i

b

l

e

r

e

m

a

i

ns

;

x

T

an

k

c

l

ean

i

n

g

and

th

e d

i

s

ch

a

rg

e

of

t

an

k

w

as

h

i

n

g

s

c

an

o

n

l

y

b

e

c

a

rr

i

ed

out

u

nde

r

th

e

s

urv

e

ill

an

c

e

of

an a

pprov

ed

MA

R

P

OL S

urv

e

yor

,

as

th

e

t

an

k

w

as

h

i

n

g

s

a

r

e

c

l

assed

as

s

p

e

c

i

a

l

w

as

t

e

.

4

.

4

.

3 B

rine (NaCl

,

KCl

,

CaCl

,

Ca

B

r)

B

r

i

ne

,

g

ene

r

a

ll

y

,

h

as

a

h

a

z

a

r

d

c

a

t

e

gory

of

Xi – i

rr

i

t

an

t

.

C

o

n

t

a

ct

w

i

th

th

e

s

ki

n

or

e

y

es

shall

b

e

a

vo

i

ded

and

v

a

pour

s

,

fum

es

,

s

pr

a

y or

g

as

shall

n

ot b

e

i

n

h

a

l

ed

.

Ca

l

c

i

um

B

rom

i

de

(

Ca

B

r

)

and

f

l

u

i

ds

co

n

t

a

i

n

i

n

g

B

rom

i

des

a

r

e

e

x

tr

e

m

e

l

y

h

a

rmfu

l

wh

en

th

e

y m

a

k

e

co

n

t

a

ct w

i

th

th

e

s

ki

n

or

e

y

es

.

N

aC

l, K

C

l,

CaC

l

b

ased

B

r

i

nes

a

r

e

co

ns

i

de

r

ed

to

b

e

of

l

ow

/

m

ed

i

um

r

i

s

k.

B

r

i

ne

i

s

n

o

n

-

f

l

a

mm

a

b

l

e

w

i

th

a n

o

n

-

de

t

e

rm

i

ned

f

l

as

h po

i

n

t

.

T

h

e

Control of Substances Hazardous to Health (COSHH) Regulations

assess

m

en

t

and

MSDS shall

a

l

w

a

y

s

b

e

co

ns

u

l

t

ed

.

Prop

e

r

and

corr

e

ct PPE

shall

b

e

wor

n

a

t

a

ll

t

i

m

es

wh

en

wor

ki

n

g w

i

th

B

rom

i

de

b

ased

f

l

u

i

ds

.

4

.

4

.

4 B

ase

O

il

B

ase

Oil

f

l

as

h

po

i

n

t

s

r

an

g

e

from

>

6

5

de

gr

ees C

w

i

th

an

a

uto

i

g

n

i

t

i

o

n

r

an

g

e

of

>2

3

0

de

gr

ees C

and

shall

b

e

s

h

i

e

l

ded/

prot

e

ct

ed

from

a

ll i

g

n

i

t

i

o

n

s

ourc

es

.

T

h

e

COSHH

ad

v

i

c

e and

MSDS shall

a

l

w

a

y

s

b

e

co

ns

u

l

t

ed

.

B

ase

Oil

h

as

a

h

a

z

a

r

d

c

a

t

e

gory of

“H

a

rmfu

l”,

w

i

th

l

u

n

g

da

m

a

g

e

po

ss

i

b

l

e

i

f

s

w

a

ll

ow

ed

.

C

o

n

t

a

ct w

i

th

s

ki

n

and

e

y

es

shall

b

e

a

vo

i

ded

and

i

n

h

a

l

a

t

i

o

n

of v

a

pour

fum

es

or

s

pr

a

y

and

g

as

i

s

h

a

rmfu

l

and

w

ill

c

a

u

se

l

u

n

g

and

r

es

p

i

r

a

tory

da

m

a

g

e

.

H

and

,

e

y

e

and

s

ki

n

prot

e

ct

i

o

n

shall

b

e

i

n

p

l

a

c

e

and

an

a

pprov

ed

r

es

p

i

r

a

tor

shall

b

e

u

sed

wh

en

en

t

e

r

i

n

g

an

y

co

n

f

i

ned

s

p

a

c

e

th

a

t h

as

co

n

t

a

i

ned

B

ase

Oil.

4

.

4

.

5

O

il

B

ased Mud (

O

B

M)

Oil B

ased

Mu

d

d

o

es

n

ot

h

a

v

e

a

h

a

z

a

r

d

c

a

t

e

gory

as

s

uch

but

ea

ch

i

nd

i

v

i

d

u

a

l

compo

nen

t

h

as

a

h

a

z

a

r

d

c

a

t

e

gory

.

T

h

e

f

l

as

h

po

i

n

t

of

Oil B

ased

Mu

d

i

s

de

p

enden

t

o

n

th

e

b

ase

o

il

u

sed

but w

ill

b

e

>

6

5

de

gr

ees C

°

and

shall

b

e

s

h

i

e

l

ded/

prot

e

ct

ed

from

a

ll i

g

n

i

t

i

o

n

s

ourc

es

.

T

h

e

COSHH

assess

m

en

t

and

MSDS shall

a

l

w

a

y

s

b

e

co

ns

u

l

t

ed

.

N

a

u

sea

and

h

eada

ch

es

c

an

occur

i

f

e

x

c

ess

i

v

e

e

x

po

s

ur

e

occur

s

.

C

o

n

t

a

ct w

i

th

s

ki

n and

e

y

es

shall

b

e

a

vo

i

ded

as

w

e

ll

as

i

n

h

a

l

a

t

i

o

n

of v

a

pour

,

fum

es

,

s

pr

a

y or

g

as

.

H

and

,

e

y

e and

s

ki

n

prot

e

ct

i

o

n

shall

b

e

i

n

p

l

a

c

e and an

a

pprov

ed

r

es

p

i

r

a

tor

ut

ili

sed

.

Ve

r

s

i

o

n

S

F

(BOS-

P

RD-0

3

.900

6

01-

v

e

r

.0

4

) O

r

i

g

i

na

l

da

t

e

: 19

/

0

6/

2012.

Ve

r

s

i

o

n

da

t

e

:

3

1

/

12

/

201

5

.

Va

li

d

v

e

r

s

i

o

n

o

n

l

y

o

n

QM

S

s

i

t

e

.

Un

co

n

tro

ll

ed

d

ocum

en

t

wh

en

pr

i

n

t

ed

.

Proc

ed

ur

e

pr

e

p

a

r

ed

by

: BOS

H

ead

of

O

p

e

r

a

t

i

o

ns

.

Approv

ed

by

: BOS

H

ead

of

O

p

e

r

a

t

i

o

ns

.

Va

li

da

t

ed

by

: BOS

Qu

a

li

ty

R

e

pr

esen

t

a

t

i

v

e

.

7 /

1

8

381